Skip to main content

Ruthenium

Source of the photo
http://periodictable.com/Elements/044/index.html
Author of the description
Gruiz Katalin

Atomic number

44

Atomic mass

101.1 g.mol -1

Electronegativity according to Pauling

2.2

Density

12.2 g.cm-3 at 20°C

Melting point

2250 °C

Boiling point

4150 °C

Vanderwaals radius

0.135 nm

Isotopes

11

Electronic shell

[ Kr ] 4d7 5s1

Energy of first ionisation

722.4 kJ.mol -1

Energy of second ionisation 1620 kJ.mol -1
Energy of third ionisation 2747 kJ.mol -1

Standard Potential

0.45 V

Discovered by

Karl Klaus in 1844

 

 


Ruthenium, together with rhodium, palladium, osmium, iridium, and platinum form a group of elements referred to as the platinum group metals (PGM).

Ruthenium is a hard, white metal. It does not tarnish at room temperatures, but oxidises in air at about 800°C. The metal is not attacked by hot or cold acids or aqua regia, but when potassium chlorate is added to the solution, it oxidises explosively. It dissolved in molten alkalis.

Applications

Ruthenium demand is rising: the metal find use in the electronic industry (50%) and the chemical industry (40%), with smaller amounts being used in alloying. In electronics it used to be used mainly for electrical contacts but most now goes into chip resistors. In the chemical industry it is used in the anodes for chlorine production in electrochemical cells.

The metal is used as a hardener for palladium and platinum and added in small amounts improves the corrosion resistance of titaniumin. It is used in electrical contact alloys and filaments, in jewelry, in pen nibs, and in instrument pivots. It is also used in alloys with cobalt, molybdenum, nickel, tungsten, and other metals. Ruthenium compounds are used to color ceramics and glass.
Ruthenium is also a versatile catalyst, used for instance in the removal of H2S from oil refineries and from other industrial processes, for the production of ammonia from natural gas, and for the production of acetic acid from methanol.
Some ruthenium complexes absorb light throughout the visible spectrum and are being actively researched in various, potential, solar energy technologies.